# How to Use the McCabe-Thiele Method for Fractional Distillation

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This Demonstration shows how to use the McCabe–Thiele method to determine the number of equilibrium stages needed to separate a binary mixture (methanol and water) in a distillation column.

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Contributed by: Rachael L. Baumann (February 2017)

Additional contributions by: John L. Falconer

(University of Colorado Boulder, Department of Chemical and Biological Engineering)

Open content licensed under CC BY-NC-SA

## Snapshots

## Details

The equilibrium curve is calculated using the modified Raoult's law:

,

,

where and are the liquid and vapor mole fractions ( for methanol, for water), , , is total pressure, and is the saturation pressure, which is calculated using the Antoine equation:

,

where is temperature and , and are constants.

The activity coefficients are calculated using the two-parameter Margules model:

,

,

where and are the Margules parameters for a methanol/water mixture.

The operating line for the rectifying section from stages 1 to is found from a material balance:

,

,

where and are the liquid and vapor flow rates in the rectifying section, is the distillate flow rate, and is the mole fraction of methanol in the distillate stream.

Because of constant molar overflow (CMO), the reflux ratio is the same everywhere. Combining with a material balance around the total condenser, , the operating line can be written in terms of the reflux ratio:

.

The operating line for the stripping section from stages to is found from a material balance:

,

,

where and are the liquid and vapor flow rates in the stripping section, is the bottoms flow rate, and is the mole fraction of methanol in the bottoms stream.

The boilup ratio is constant everywhere. Combining with a material balance around the partial reboiler, , the operating line for the stripping section can be written in terms of the boilup ratio:

.

Typically the feed operating line (-line) is used to locate the stripping operating line. The parameter is defined as the ratio of the increase in molar reflux rate across the feed stage to the molar feed rate:

,

where is the feed flow rate.

One point on the -line is the intersection of the rectifying and stripping section operating lines; thus the -line can be derived from:

.

Combining an overall material balance around the column , a material balance around the feed stage and the definition of , the -line is:

,

where is the mole fraction of methanol in the feed.

Once the operating lines and compositions are plotted on the - diagram, the number of equilibrium stages needed to achieve a bottoms composition of is determined. Start at the top of the column at . A material balance in between stages (operating line) is used to calculate from :

.

Based on the material balance, has to be balanced with so a horizontal line (green) is drawn from on the - line to on the equilibrium curve. For the stripping section, the material balance is .

On each stage, the liquid and vapor streams are in VLE, so the stream has a liquid composition and a vapor composition . A vertical line (purple) is drawn from the equilibrium curve at to the - line at . This process is repeated until the bottoms composition is reached. Typically the number of stages drawn is not a whole number. The partial reboiler is considered an equilibrium stage. View the screencast videos [2, 3] for a step-by-step explanation of the McCabe–Thiele method. The screencast video [4] explains how material balances and VLE data are used to determine the number of equilibrium stages.

References

[1] J. D. Seader, E. J. Henley and D. K. Roper, *Separation Process Principles: Chemical and Biochemical Operations*, 3rd ed., Hoboken, NJ: Wiley, 2011.

[2] University of Colorado Boulder. *McCabe–Thiele Graphical Method Example Part 1* [Video]. (Feb 2, 2017) www.youtube.com/watch?v=Cv4KjY2BJTA.

[3] University of Colorado Boulder. *McCabe–Thiele Graphical Method Example Part 2* [Video]. (Feb 2, 2017) www.youtube.com/watch?v=eIJk5uXmBRc.

[4] University of Kentucky. *McCabe–Thiele: Stepping Off Stages* [Video]. (Feb 2, 2017) www.youtube.com/watch?v=rlg-ptQMAsg.

## Permanent Citation