9712

Partial Molar Enthalpy

The enthalpy of a binary mixture of and is plotted as a function of the mole fraction of component . For an ideal solution, the enthalpy of the mixture is a linear function of the molar enthalpies of the pure components. For a non-ideal solution, you can vary a parameter that describes the deviation from ideality. One can define partial molar enthalpies, which are obtained by drawing a tangent at the value of the mole fraction of the solution. The intersections of this tangent with the axis at and correspond to the partial molar enthalpies of and , respectively. You can also vary the mole fraction of in the mixture, as indicated by the dot on the curve.
  • Contributed by: Simon M. Lane
  • (University of Colorado Boulder, Department of Chemical and Biological Engineering)

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= partial molar enthalpy of component (kJ/mol)
= partial molar enthalpy of component (kJ/mol)
= molar enthalpy of component (kJ/mol)
= molar enthalpy of component (kJ/mol)
= molar enthalpy of mixture (kJ/mol)
, equation for enthalpy of non-ideal binary mixture
= non-ideal parameter
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