Kinetic and Thermodynamic Control of Electrophilic Addition Reactions
This Demonstration shows the effect of thermodynamics and kinetics on electrophilic addition reactions producing dienes. The following reaction is considered:[more]
Reaction progress can be viewed using the "time" slider; the quantities of the products are proportional to the size of the balls. Using the "reactions" buttons, it is possible to choose a reaction and follow its progress. Use the checkbox to visualize the thermal energy of the molecules and compare it to the activation energies.[less]
Snapshot 1: the lower thermal energy promotes the predominance of the 1,2-addition compared to the 1,4-addition
Snapshot 2: the higher thermal energy promotes the predominance of the 1,4-addition compared to the 1,2-addition
Snapshot 3: increasing the temperature causes the transfer of the double bond
 R. T. Morrison and R. N. Boyd, Organic Chemistry, 3rd ed., Boston: Allyn and Bacon, 1973.
 Chemistry LibreTexts. "16.10: Electrophilic Addition: 1,2- versus 1,4-Addition." (Feb 16, 2018) chem.libretexts.org/?title=Textbook_Maps/Organic_Chemistry_Textbook_Maps/Map:_Organic_Chemistry_(Smith)/Chapter_16:_Conjugation,_Resonance,_%26_Dienes/16.10:_Electrophilic_Addition:_1,2-_Versus_1,4-Addition.