Periodic and Damped-Oscillatory Behavior of the Oregonator

Initializing live version
Download to Desktop

Requires a Wolfram Notebook System

Interact on desktop, mobile and cloud with the free Wolfram Player or other Wolfram Language products.

This Demonstration shows the oscillatory behavior of the Belousov–Zhabotinsky reaction (BZ reaction), which was modeled by Field, Körös, and Noyes (FKN) in the early 1970s. This is now known as the Oregonator model. It is based on the following mechanism:

[more]

,

,

,

,

where , , , , , and .

The law of mass action yields the following nondimensional 3×3 system of nonlinear ODEs:

,

,

,

where , , , and .

There is periodic behavior for , which is confirmed by (1) the sustained oscillations in the time series plot and (2) the limit-cycle in the time-delay reconstruction diagram (both plots are shown in red). This latter diagram is obtained by plotting versus with arbitrarily taken equal to 0.01. A transition occurs at approximately with time series exhibiting damped oscillation for (plot shown in blue) and the time-delay reconstruction diagram collapsing to a single blue point.

[less]

Contributed by: Housam Binous, Brian G. Higgins, and Ahmed Bellagi (February 2013)
Open content licensed under CC BY-NC-SA


Snapshots


Details

References

[1] I. R. Epstein and J. A. Pojman, An Introduction to Nonlinear Chemical Dynamics: Oscillations, Waves, Patterns, and Chaos, New York: Oxford University Press, 1998.

[2] A. Barnett. "Math 53: Chaos! - Fall 2011." (Feb 21, 2013) www.math.dartmouth.edu/~m53f11.



Feedback (field required)
Email (field required) Name
Occupation Organization
Note: Your message & contact information may be shared with the author of any specific Demonstration for which you give feedback.
Send