Separation of a Reactive Quaternary Mixture in a Distillation Column

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Consider a quaternary mixture of components ,
,
, and
with relative volatilities
,
, and
. This mixture is subject to an equilibrium-limited chemical reaction
with reaction rate
, where the equilibrium constant
. This mixture is fed to a reactive distillation column such that the total number of plates is 17. The feed stage location is stage number 10, the reactive stages are from stage 6 to stage 14, and the feed composition is equimolar in
and
(i.e., the feed is composed of 50 mole %
and 50 mole %
). The feed, a saturated liquid, has a flow rate of 100 kmol/hr. For simplicity, constant molal overflow (CMO) is assumed and heat effects are neglected.
Contributed by: Housam Binous, Manel Selmi, Ines Wada, and Ahmed Bellagi (March 2011)
Open content licensed under CC BY-NC-SA
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For more information, see
M. F. Doherty and M. F. Malone, Conceptual Design of Distillation Systems, New York: McGraw–Hill, 2001.
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