Steady-State Binary Fickian Diffusion
This Demonstration shows a calculation of the concentration profile and the mass flow rate of octane vapor through a tube in steady-state Fickian diffusion. Pure liquid octane is at the bottom of the vertical tube, which has a diameter of 28 cm, and a stagnant layer of air is in the tube above the liquid. Air flows across the open top of the tube to remove the octane vapor; its concentration at the top is zero. Use sliders to change the total pressure, height of the tube and temperature. The octane mole fraction versus tube height curve is shown in blue when convective flux is significant and in black when it is insignificant.
Contributed by: Muqbil Alkhalaf and Rachael L. Baumann (July 2018)
Additional contributions by: Neil Hendren and John L. Falconer
(University of Colorado Boulder, Department of Chemical and Biological Engineering)
Open content licensed under CC BY-NC-SA
where is the total flux (), and , are the fluxes of and ().
The previous equation can be rearranged in the form of Fick's law by solving for :
The term accounts for the bulk flow effect, where
is the total molar concentration (),
is the ideal gas constant (),
is temperature (K),
is diffusivity (),
is the liquid mole fraction of
and is the height of the tube (m).
At quasi-steady state and with constant molar density, in integral form:
where is the mole fraction at , and is the mole fraction at .
The mole fraction variation as a function of is:
A more useful form of can be derived from the definition of the log mean:
Combining and gives:
From Dalton's law, assuming equilibrium at the liquid octane/air interface:
where is the saturation pressure (atm).
The saturation pressure is calculated from the Antoine equation:
where , and are Antoine constants.
Solve the diffusive flux equation using the boundary conditions and :
The concentration profile is
solving for ,
If the diffusive flux is greater than 90% of the total flux, then .
Finally, the molar flow rate through the top of the tube is calculated. Given that is the cross-sectional area of the tube:
The mass flow rate is then
where is the molecular weight of the compound.
 J. D. Seader, E. J. Henley and D. K. Roper, Separation Process Principles: Chemical and Biochemical Operations, 3rd ed., Hoboken, NJ: John Wiley & Sons, 2011 pp. 88–89.