Study of a Batch Reactive Rectifier

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Consider an ideal ternary mixture subject to an equilibrium-limited chemical reaction . The relative volatilities and the chemical equilibrium constant are taken as
,
, and
. Pure
is fed to a reactive rectifier and it is assumed that the reaction takes place only in the still. This Demonstration plots the distillate composition versus time for user-set values of the Damköhler number
, the reflux ratio, and the number of nonreactive stages in the rectifier. Compositions of components
,
, and
are plotted in red, green, and blue, respectively. It is clear from the snapshots that when
is high, one gets pure
, pure
, and a minor intermediate fraction, which is rich in component
. Thus, it is possible to drive the reaction conversion to very high values to recover the pure products, components
and
.
Contributed by: Housam Binous, Manel Selmi, Ines Wada, and Ahmed Bellagi (March 2011)
Open content licensed under CC BY-NC-SA
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"Study of a Batch Reactive Rectifier"
http://demonstrations.wolfram.com/StudyOfABatchReactiveRectifier/
Wolfram Demonstrations Project
Published: March 7 2011