Symmetry Breaking in the Perovskite SrTiO3

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Solid-solid phase transitions result when at least one normal mode of the system softens (i.e. becomes weaker) as the temperature decreases. Once the temperature is decreased below a critical temperature , the higher symmetry structure is no longer stable and the lattice distorts to form a new structure with lower symmetry. This results in a second-order phase transition, since the entropy and free-energy vary continuously with temperature while the heat capacity
is discontinuous at
.
Contributed by: Eric R. Bittner (March 2012)
Open content licensed under CC BY-NC-SA
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References
[1] J. F. Scott, "Soft-Mode Spectroscopy: Experimental Studies of Structural Phase Transitions," Reviews of Modern Physics, 48(1), 1974 pp. 83–128.
[2] V. L. Ginzburg and L. D. Landau, Journal of Experimental and Theoretical Physics, 20, 1950 p. 1064.
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