The Semenov Model

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Semenov developed a model that describes the thermal ignition phenomenon quantitatively. Assume that the temperature, , of the reacting system is constant and uniform across the volume of the system and assume that the walls of the system and the ambient external temperature,
, are the same. The steady-state temperature is obtained by setting the heat production term (i.e., the left-hand side of the equation) equal to the heat losses term, which is mainly due to convection between the system and the surroundings (i.e., the right-hand side of the equation):
Contributed by: Housam Binous and Brian G. Higgins (January 2012)
Open content licensed under CC BY-NC-SA
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G. Nicolis, Dynamique chimique: Thermodynamique, cinétique et mécanique statistique, Paris: Dunod, 2005.
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