Extractive Distillation Column to Separate Isopropyl Alcohol from Water

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The binary mixture of water and isopropyl alcohol (isopropanol or propan-2-ol) presents a positive azeotrope at 1 atm. This azeotrope contains mole % isopropanol. It is possible to break this azeotrope using extractive distillation. Possible entrainers include: (1) 1,2-ethanediol or ethylene glycol, (2) DSMO (or dimethyl sulfoxide), (3)
-methyl-2-pyrrolidone or NMP, (4)
-methyl-2-piperidone, and (5)
-methyl-6-caprolactam.
Contributed by: Housam Binous (December 2010)
(Kind Fahd University Petroleum & Minerals)
Open content licensed under CC BY-NC-SA
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For more information, see S. Arifin and I–L. Chien, Design and Control of Isopropyl Alcohol Dehydration via Homogeneous Azeotropic Distillation Using Dimethyl Sulfoxide as Extractive Agent.
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