Metallicity Condition and Electronic Density of States in Achiral Single-Walled Carbon Nanotubes

Requires a Wolfram Notebook System

Interact on desktop, mobile and cloud with the free Wolfram CDF Player or other Wolfram Language products.

Requires a Wolfram Notebook System

Edit on desktop, mobile and cloud with any Wolfram Language product.

This Demonstration plots the electronic density of states (DOS) computed from the tight-binding method for zigzag () and armchair () single-walled carbon nanotubes (SWNTs). The spikes in the electronic DOS profile are called van Hove singularities (vHs) and originate from the different values of the azimuthal band quantum number . The total number of allowed values is determined by the number of graphene unit cells inside the SWNT cell, which is always for achiral SWNTs. By playing with the chiral pairs , you can verify the metallicity condition for these achiral SWNTs: for metallic SWNTs and for semiconducting SWNTs. For metallic SWNTs the electronic DOS is nonzero at the Fermi level, whereas for semiconducting SWNTs, a gap occurs at the Fermi level. Armchair SWNTs are always metallic for any . By changing the sliders related to the tight-binding parameters and you can change the value of the energy at which the vHs occur and the asymmetry of the electronic structure with respect to the Fermi level ().

Contributed by: Jessica Alfonsi (University of Padova, Italy) (June 2011)
Open content licensed under CC BY-NC-SA


Snapshots


Details

Electronic density of states:

Snapshot 1: for a semiconducting zigzag (7,0) SWNT:

Snapshot 2: for a metallic zigzag (9,0) SWNT:

Snapshot 3: for an armchair (6,6) SWNT, always metallic:

The analytical expressions used in the program were taken from [1].

Reference

[1] A. T. Costa, Jr., D. F. Kirwan, and M. S. Ferreira, "Indirect Exchange Coupling between Magnetic Adatoms in Carbon Nanotubes," Physical Review B 72(8), 2005. doi:10.1103/PhysRevB.72.085402.



Feedback (field required)
Email (field required) Name
Occupation Organization
Note: Your message & contact information may be shared with the author of any specific Demonstration for which you give feedback.
Send