This Demonstration plots the electronic density of states (DOS) computed from the tight-binding method for zigzag () and armchair () single-walled carbon nanotubes (SWNTs). The spikes in the electronic DOS profile are called van Hove singularities (vHs) and originate from the different values of the azimuthal band quantum number . The total number of allowed values is determined by the number of graphene unit cells inside the SWNT cell, which is always for achiral SWNTs. By playing with the chiral pairs , you can verify the metallicity condition for these achiral SWNTs: for metallic SWNTs and for semiconducting SWNTs. For metallic SWNTs the electronic DOS is nonzero at the Fermi level, whereas for semiconducting SWNTs, a gap occurs at the Fermi level. Armchair SWNTs are always metallic for any . By changing the sliders related to the tight-binding parameters and you can change the value of the energy at which the vHs occur and the asymmetry of the electronic structure with respect to the Fermi level ().