Eigenfunctions of a 1D Quantum System with Adjustable Potential

Initializing live version
Download to Desktop

Requires a Wolfram Notebook System

Interact on desktop, mobile and cloud with the free Wolfram Player or other Wolfram Language products.

This Demonstration shows the stationary states (eigenvalues and eigenfunctions of the Hamiltonian) for a quantum particle in one dimension under the influence of an adjustable potential. The potential is a sum of two components: (1) a power potential, symmetric for even exponent (such as the default value 2 for the harmonic oscillator) and antisymmetric for odd exponent (e.g., 1 for the inclined plane) and (2) a Gaussian potential barrier. If the barrier (you can select the height, width, and center position) is set appropriately, it turns the harmonic oscillator potential into a double-well potential, an extensively studied quantum-mechanical model system. For the stationary states, you can choose between three graphical representation modes. The most detailed information is obtained in the first of these modes, showing the potential as well as the real and imaginary parts of the eigenfunctions. You can select the stationary state to be displayed. The index shows how increasingly higher excited states change the geometrical features of the wavefunctions. You can also observe how the energy eigenvalue increases correspondingly.

Contributed by: Ulrich Mutze (January 2015)
Open content licensed under CC BY-NC-SA



This Demonstration is based on the representation of the Hamiltonian operator as a numerical square matrix and on the Mathematica function EigenSystem to determine the eigenvalues and eigenfunctions of this matrix numerically. Unlike analytical methods, the form of the potential is not restricted. The dynamical evolution of initially bell-shaped states in exactly the potentials of the present Demonstration is studied in the Demonstration "Quantum Dynamics in 1D" by the present author.

Snapshot 1: symmetric ground state in a symmetrical double-well potential

Snapshot 2: antisymmetric ground state in a symmetrical double-well potential; the lowest energy value is thus degenerate

Snapshot 3: ground state in an asymmetrical double-well potential; the lowest energy value is not degenerate

Snapshot 4: first excited state in an asymmetrical double-well potential

Snapshot 5: a highly excited state in a strongly asymmetrical double-well potential

Snapshot 6: all stationary states of the strongly asymmetrical double-well potential

Snapshot 7: all energy values of the particle in the strongly asymmetrical double well potential

Feedback (field required)
Email (field required) Name
Occupation Organization
Note: Your message & contact information may be shared with the author of any specific Demonstration for which you give feedback.